What does below chemistry rebus means?

I am the largest in my family of fifty.
The youngest of our family lives separately from the rest of the family and so do I.
I am regarded as harsh and tough.
I am so large, you cut me in two equal halves,
each half would still be larger than the second largest member of the family.
Who am I?

Which tank will fill first?

A man is looking at a photograph of someone. His friend asks who it is. The man replies, “Brothers and sisters, I have none. But that man’s father is my father’s son.” Who was in the photograph?

I have no life, but I can die. What am I?

What English word has three consecutive double letters?

You are on a Boat in the mid of a river. You have two cigarettes with you. One of these two you have to light, how will you light the cigarette?

You have a three-gallon and a five-gallon measuring device. You wish to measure out four gallons.

If,

A = 1

B = 2

C = 3

...

...

Z = 26.

Based on above rule, you need to find an eleven letter word whose letter sum is equal to 52.

Can you solve this tricky maths equation problem by replacing it? mark with the correct symbol?

19834 -----: 187
15921 -----: 153
17561 -----: 139
13734 -----: ???