What does below chemistry rebus means?

John was running from 40 thieves. John has got 3 gold boxes which weigh as 4kg, 2kg, and 1kg respectively. A witty man asked John to stay with him for seven days in exchange for 1kg gold per day. John needs to stay there for seven days and also do not want to give the witty man any advance. How can John pay for his seven days stay?

What has no start, end, or centre?

What is at the end of a rainbow?

_ _ _ IE _ _
_ _ _ IE _
_ _ IE _ _
_ _ IE _
_ _ _ _ IE

Like you see, some letters have gone missing from these words that contain the IE pair at some or the other place. The letters that will be used to fill the blanks are given below. Use them and form meaningful words. Can you do that?

A, C, D, F, H, K, L, M, N, N, O, R, R, S, S, S, T, T, Y and Y.

There is a box in which distinct numbered balls have been kept. You have to pick two balls randomly from the lot.

If someone is offering you a 2 to 1 odds that the numbers will be relatively prime, for example
If the balls you picked had the numbers 6 and 13, you lose $1.
If the balls you picked had the numbers 5 and 25, you win $2.

Will you accept that bet?

During a secret mission, an agent gave the following code to the higher authorities
AIM DUE OAT TIE MOD

However, the information is in one word only and the rest are fake. To assist the authorities in understanding better, he also sent them a clue, If I tell you any one character of the code, you can easily find out the number of vowels in the codeword.

Can you find out the code word?

A man is trapped in a room. The room has only two possible exits doors. Through the first door there is a room constructed from magnifying glass. The blazing hot sun instantly fries anything or anyone that enters. Through the second door there is a fire-breathing dragon. How does the man escape?

There’s a girl who has a large family. She has an equal amount of brothers and sisters, but each brother only has half as many brothers and sisters. What’s the correct amount of brothers and sisters?

There is a number which when you multiply by 3 and subtract 2 from the result, then the resulting number is the reverse of the actual number.

What is the smallest number that stands true on the statement?