What does below chemistry rebus means?

Find a 9-digit number, which you will gradually round off starting with units, then tenth, hundred etc., until you get to the last numeral, which you do not round off. The rounding alternates (up, down, up ...). After rounding off 8 times, the final number is 500000000. The original number is commensurable by 6 and 7, all the numbers from 1 to 9 are used, and after rounding four times the sum of the not-rounded numerals equals 24.

A man and a dog were going down the street. The man rode, yet walked. What was the dog’s name?

A maths symbol is hidden in the below Bar Graph. Can you decipher it?

A finger goes in me. You fiddle with me when you're bored. The best man always has me first. What am I?

When a clock is observed, the hour hand is at a minute mark and the minutes hand is six minutes ahead of it.

When the clock is observed again after some time, the hour hand is precisely on a different minute mark and the minute hand is seven minutes ahead of it.

Can you calculate how much time has elapsed between the two observations?

Detective John was investigating a murder in China.
It was a difficult case, and John was completely stumped until he noticed a message sent to him by the killer cunningly hidden in a newspaper advertisement selling Car Licence Plates.
Detective John thought about it for a while, and when he had solved the puzzle, immediately arrested the guilty man.

Q1) How did John know the advert was a clue for him?

Q2) Solve the code and tell me who John arrested.

This is the newspaper advert (Car licence plates for sale) that Detective John saw.

Plates For Sale;

[W 05 NWO]
[H 13 HSR]
[O 05 EBM]
[D 08 UNE]
[U 10 HTY]
[N 04 BRE]
[N 16 TTE]
[I 26 LHC]
[T 10 AEE]
[I 26 CNA]
[X 22 VDA]

You can see three almost identical images below. Can you spot the odd one out from them?

At my favorite fruit stand,
an orange costs 18,
a pineapple costs 27,
and a grape costs 15.
Using the same logic, can you tell how much a mango costs?

What is the Surname of Barbie Doll?