Decode this picture on T-Shirt and tell what it says ?

In the given picture, you can find two letters missing. When two particular letters are placed in the missing spots, you get an eight-letter word while reading in the anti-clockwise direction. Can you find out the missing letters and the missing word eventually?

The Puzzle: Here is a famous prize problem that Sam Loyd issued in 1882, offering $1000 as a prize for the best answer showing how to arrange the seven figures and the eight 'dots' .4.5.6.7.8.9.0. which would add up to 82

I have nine bottles of wine and one of the nine bottles is poisoned.
I need to find the poisoned bottle with two facts
(1) Poison is deadly, only a sip will cost death
(2) I have two mice to do so.

How should I do it?

Most people think of me as money. But when they find me in the water, they won’t get any money out of me. What am I?

Can you identify the famous TV character from the rebus below?

In the Chess Board picture below white army is arranged. You need to add a black army on the board such that no piece is under any threat.
Note: Army comprised of 1 king, 1 queen, 2 rooks, 2 bishops, 2 knights, and 8 pawns.

Can you fill the blank with the correct number?

6 30 870 756030 _____

There was a minor accident with a doctor's son but the doctor noticed no major injury. After the treatment, the father of that doctors son is sitting with the son of the doctor without the doctor being in the room.

How can this be possible?

John was working on a Chemical Mixture whose weight comprise 90% liquid and 10% solid. The total weight of the mixture is 20 pounds. After a while, John noticed that some of the liquid evaporated and now the liquid comprises just 50% of the weight.

What is the weight of the chemical mixture now?